CHEMICAL THERMODYNAMICS  (KIM 252E)

SPRING SEMESTER     (2016/17)

INSTRUCTOR:       

            Oğuz OKAY

TEXTBOOKS:         

 Physical Chemistry    (LEVINE and ATKINS)

CLASS HOURS:                    

                        TUESDAY  13:30-16:30                  

PLACE:                    

                                     D203

GRADING:             

MIDTERMS (25 % each),  FINAL (50 %)

 

 SCHEDULE AND CONTENT

1st MIDTERM RESULTS

FINAL EXAM RESULTS

CLASS LIST

2nd MIDTERM RESULTS

Past Exam Questions (KIM 252)

Weight of the Course Work:

Midterms:      25% each (Oct.24, and Dec. 5).

Final:          50%

Week

Date

Topics

     1

      7.2

Introduction

2

 

    14.2
 

Physical chemistry and main branches, chemical thermodynamics, definitions, units, ideal behavior of gases, deviations from ideality, excluded volume and intermolecular interactions, derivation of van der Waals and Virial equations

3

    21.2

Calculus, derivatives, total differential, state functions, thermal expansion coefficient, isothermal compressibility, derivation of the Virial equation from van der Waals equation, Boyle temperature, PV isotherm of real gases, critical point, critical pressure and derivation of van der Waals constants. 

4

    28.2

The first law of thermodynamics, work, heat, reversible and irreversible processes, internal energy, enthalpy

5

      7.3

Cp, Cv, internal pressure, Joule and Joule - Thomson experiments, application of the first law in ideal gas processes, isothermal and adiabatic processes.

     6

   14.3

 Spontaneous processes, conversion of heat into useful work, the second law of the thermodynamics, thermodynamic efficiency, Carnot cycle, entropy.

7

   21.3

1st  midterm exam 

-

   28.3

No lecture

8

     4.4

Entropy changes in various processes, entropy change during mixing, Boltzman equation, entropy changes in the system, in the environment and in the universe, heat pump and refrigerator, examples

 9

   11.4

The third law of thermodynamics, absolute zero, cryogenics, Gibbs and Helmholtz free energies, Gibbs equations, Maxwell relations, examples

10

   18.4

Calculations of the changes in internal energy, enthalpy, entropy, Gibbs and Helmholtz free energies in real processes using Gibbs equations and Maxwell relations.

 11

   25.4

2nd midterm exam

12

    2.5

Material equilibrium, phase and reaction equilibrium, chemical potential, extent of the reactions and stochiometric coefficients, osmotic pressure, examples and exercises

13

    9.5

Chemical equilibrium in gas phase reactions, equilibrium constant and its temperature dependence

14

  16.5 

Review of the topics covered, exercises. 

doorin2

 

grade

10632: KIM 252E, Chemical Thermodynamics Dersi İçin Öğrenci Listesi

Ögrenci No

Ad Soyad

Devam/ 10 ders

Final

90140226

Ahsen Sare Yalın

10

87

90150237

Aylin Kınık

8

64

90150205

Burcu Hatipoğlu

6

94

90140203

Çağrı Özsan

10

97

90140240

Damla Öztürk

7

80

90140227

Dilara Güntürkün

10

98

90150234

Emirhan Gençosman

10

70

90120336

Emirhan Yılmaz

0

0

90120220

Emre Özdemir

9

8

90140209

Erdal Anıl Dalgakıran

10

100

90120247

Halil Öklü

5

44

90150207

İremnaz Eyüboğlu

6

0

90150223

Kübra Kara

9

72

90150208

Mert Dinç

7

0

90100908

Reyhaneh Mohammadzadeh Barazandeh

7

0

90150203

Saadet Elif Duran

4

0

90140222

Sena Çiftbudak

6

0

90140238

Serra Ebru Öztürk

8

0